Novel concepts in directed biaryl synthesis part 83 - Synthesis and atropo-diastereoselective ring cleavage of a [Cp*Ru]-complexed biaryl lactone: Experimental and computational investigations

Authors
Bringmann, G Wuzik, A Stowasser, R Rummey, C Gobel, L Stalke, D Pfeiffer, M Schenk, WA
Citation
G. Bringmann et al., Novel concepts in directed biaryl synthesis part 83 - Synthesis and atropo-diastereoselective ring cleavage of a [Cp*Ru]-complexed biaryl lactone: Experimental and computational investigations, ORGANOMETAL, 18(24), 1999, pp. 5017-5021
Citations number
35
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
18
Issue
24
Year of publication
1999
Pages
5017 - 5021
Database
ISI
SICI code
0276-7333(19991122)18:24<5017:NCIDBS>2.0.ZU;2-T
Abstract
The planar-chiral biaryl lactone complex 5b is cleaved highly atropo-diaste reoselectively by simple O-nucleophiles. Toward H-nucleophiles, it shows a different reactivity behavior consistent with DF calculations using the Fuk ui function.