Synthesis of alpha, gamma-disilylated amines from beta-silylated imines

Authors
Bolourtchian, M Badrian, A
Citation
M. Bolourtchian et A. Badrian, Synthesis of alpha, gamma-disilylated amines from beta-silylated imines, PHOSPHOR SU, 152, 1999, pp. 129-134
Citations number
13
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
ISSN journal
10426507 → ACNP
Volume
152
Year of publication
1999
Pages
129 - 134
Database
ISI
SICI code
1042-6507(1999)152:<129:SOAGAF>2.0.ZU;2-B
Abstract
Lithium-promoted reductive coupling of beta-silylated imines (1) with trime thylsilyl chloride (TMSCI,2) in THF at 0-10 degrees C fives the correspondi ng alpha, gamma-disilylated amines in good yields.