Synthesis and mechanism of aminophosphonate formation in the presence of ultrasound

Authors
Hubert, C Garrigues, B Munoz, A
Citation
C. Hubert et al., Synthesis and mechanism of aminophosphonate formation in the presence of ultrasound, PHOSPHOR SU, 152, 1999, pp. 229-240
Citations number
14
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
ISSN journal
10426507 → ACNP
Volume
152
Year of publication
1999
Pages
229 - 240
Database
ISI
SICI code
1042-6507(1999)152:<229:SAMOAF>2.0.ZU;2-G
Abstract
Phosphonates 1a, 1b, 1c react with imine 2 following a polar mechanism with out any ultrasonic effect. Starting with phosphonate 1d, a more complex (polar and radical) mechanism has been pointed our. This latter reaction was accelerated under ultrasound .