The formation of lamella microphases in symmetric neutral-ionic block copol
ymers has been investigated by constant volume-constant temperature (NVT) m
olecular-dynamics computer simulations using a generic coarse-grain model.
Computations of counterion diffusion, pressure tensor, and the anisotropy o
f the structure factor are used to characterize the order-disorder transiti
on (ODT). There is strong counterion condensation on the ionic blocks at te
mperatures well above the ODT; this creates a slight imbalance in the volum
e composition of the two blocks and results in a perforated lamella structu
re in the microphase. Below the ODT counterion diffusion is decoupled from
the chain motions but is strongly anisotropic due to the microphase morphol
ogy. The high counterion diffusional mobility is discussed in terms of the
relatively low value of the glass transition for the ionic blocks. [S1063-6
51X(99)05711-6].