An integro-differential equation is proposed that generalizes the plasma-sh
eath (Langmuir-Tonks) equation to include charge. exchange between ions and
neutrals in a discharge plasma and makes it possible to correctly analyze
how the discharge evolves from the regime of collisionless ion motion to th
e diffusive regime in pure gases with allowance for the space charge in the
sheath at the plasma boundary. The integro-differential equation is solved
numerically, and the ionization rate is calculated as a function of the ra
tio between the ion mean free path and the characteristic discharge dimensi
on. The ion energy distribution function in the positive column of a discha
rge plasma is computed. The parameter range in which the positive column ca
n exist is examined, and the limits of applicability of different discharge
models are: analyzed depending on the relations between the ion mean free
path, Debye length, and discharge dimension.