Thermal stability in air is an important requirement for many industrial ap
plications of PVD hard coatings. The objective of this study is to evaluate
the thermal stability of a number of PVD coatings with respect to their me
chanical, physical and chemical properties. The coatings studied were TiN,
TiCN, Ti diamond-like carbon and Graphit-iC (TM) carbon, which were deposit
ed on steel substrates by magnetron sputtering. The performance of these co
atings was evaluated both before and after heat treatment (up to 500 degree
s C) in air. The initiation of thermal decomposition of the coating was mar
ked by a decrease in the coating wear life, as observed using pin-on-disk m
easurements. Other tribological properties assessed were friction: adhesion
and hardness. Optical microscopy and glancing angle X-ray diffraction were
also used to monitor the influence of the thermal treatment on the coating
s. (C) 1999 Elsevier Science S.A. All rights reserved.