[2,3]-Sigmatropic rearrangement of allylic sulfur ylides derived from trimethylsilyldiazomethane (TMSD)

Authors
Aggarwal, VK Ferrara, M Hainz, R Spey, SE
Citation
Vk. Aggarwal et al., [2,3]-Sigmatropic rearrangement of allylic sulfur ylides derived from trimethylsilyldiazomethane (TMSD), TETRAHEDR L, 40(50), 1999, pp. 8923-8927
Citations number
14
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
40
Issue
50
Year of publication
1999
Pages
8923 - 8927
Database
ISI
SICI code
0040-4039(199912)40:50<8923:[ROASY>2.0.ZU;2-4
Abstract
Trimethylsilyldiazomethane reacts with allylic sulfides in the presence of catalytic quantities of Rh-2(OAc)(4) (1 mol%) to give homoallylic sulfides in good yields and with high diastereoselectivity. (C) 1999 Published by El sevier Science Ltd. All rights reserved.