Citation
W. Xiao et al., 1,1 '-diacetylferrocene bis(thiosemicarbazone) monohydrate, ACT CRYST C, 55, 1999, pp. 1762-1764
Citations number
15
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701
→ ACNP
Volume
55
Year of publication
1999
Part
11
Pages
1762 - 1764
Database
ISI
SICI code
0108-2701(19991115)55:<1762:1'BM>2.0.ZU;2-W
Abstract
X-ray analysis reveals that both thiosemicarbazone groups of the title comp
ound, [Fe(C8H10N3S)(2)]. H2O, are in the keto tautomeric form and that the
configuration of the azomethine C=N double bond is E. The two cyclopentadie
nyl rings are parallel and nearly eclipsed. The crystal structure is stabil
ized by extensive intra- and intermolecular hydrogen bonding involving the
water molecule and the thiosemicarbazone moieties.