Di-mu-azido-bis{[2-(2-aminoethyl)pyridine-N,N ']aquacopper(II)} diperchlorate

Citation
Ia. Razak et al., Di-mu-azido-bis{[2-(2-aminoethyl)pyridine-N,N ']aquacopper(II)} diperchlorate, ACT CRYST C, 55, 1999, pp. 1764-1766
Citations number
11
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
55
Year of publication
1999
Part
11
Pages
1764 - 1766
Database
ISI
SICI code
0108-2701(19991115)55:<1764:D'D>2.0.ZU;2-F
Abstract
In the title compound, [Cu-2(N-3)(2)(C7H10N2)(2)(H2O)(2)](ClO4)(2), the Cu atom is in a distorted square-pyramidal environment with the basal position s occupied by four N atoms, two from a bidentate 2-(2-aminoethyl)pyridine l igand and another two from a centrosymmetrically related azide bridge. The water molecule occupies the axial position. In the crystal, the molecules a re in a stacked arrangement and form layers connected by hydrogen bonds inv olving water molecules and perchlorate ions.