[N-acetyl-N '-methylureato(2-)-N,N '] (eta(5)-pentamethylcyclopentadienyl)(triphenylphosphine-P)iridium(III) chloroform solvate

Authors
Dinger, MB Henderson, W Oliver, AG Rickard, CEF
Citation
Mb. Dinger et al., [N-acetyl-N '-methylureato(2-)-N,N '] (eta(5)-pentamethylcyclopentadienyl)(triphenylphosphine-P)iridium(III) chloroform solvate, ACT CRYST C, 55, 1999, pp. 1778-1780
Citations number
13
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
55
Year of publication
1999
Part
11
Pages
1778 - 1780
Database
ISI
SICI code
0108-2701(19991115)55:<1778:[''(>2.0.ZU;2-U
Abstract
The title complex, [Ir(C10H15)(C4H6N2O2)(C18H15P)].-CHCl3, displays a 'pian o-stool'-type configuration of ligands, with the Ir atom in an Ir-NR-C(O)-N R' ring system. This is the first structure determination of a coordinative ly saturated iridaureylene complex.