Chloro(meso-tetrapropylporphyrinato)-iron(III)

Authors
Ohgo, Y Ikeue, T Nakamura, M
Citation
Y. Ohgo et al., Chloro(meso-tetrapropylporphyrinato)-iron(III), ACT CRYST C, 55, 1999, pp. 1817-1819
Citations number
21
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
55
Year of publication
1999
Part
11
Pages
1817 - 1819
Database
ISI
SICI code
0108-2701(19991115)55:<1817:C>2.0.ZU;2-D
Abstract
In the chloroiron(III) complex of meso-tetrapropyl-porphyrin, [Fe(C32H36N4) Cl], the Fe-III atom has slightly distorted square pyramidal coordination. The porphyrin ring shows a typical S-4-ruffled structure in addition to a n ormally observed domed core; the deviations of the meso-C and Fe atoms from the least-squares plane of the C20N4 core are 0.366(4) (maximum) and 0.578 (1) Angstrom, respectively. The average Fe-N-p bond distance is 2.063 (4) A ngstrom.