Vv. Yaminsky et Bw. Ninham, Surface forces vs. surface compositions. Colloid science from the Gibbs adsorption perspective, ADV COLL IN, 83(1-3), 1999, pp. 227-311
Interfacial phenomena associated with the surfaces of liquids are well unde
rstood in terms of surface tension and adsorption from solution. Those that
relate to surfaces of solids are not, and have been treated at a different
level of quantification. An approach based on the Gibbs equation is shown
to yield a rigorous unified treatment of phenomena in wetting transitions a
nd surface forces not encompassed by the DLVO theory. (C) 1999 Elsevier Sci
ence B.V. All rights reserved.