Resolution and synthesis of (S)-1-(2-naphthyl)ethanol with immobilized peaprotein: As a new biocatalyst

Citation
H. Nagaoka et H. Kayahara, Resolution and synthesis of (S)-1-(2-naphthyl)ethanol with immobilized peaprotein: As a new biocatalyst, BIOS BIOT B, 63(11), 1999, pp. 1991-1992
Citations number
12
Categorie Soggetti
Agricultural Chemistry","Biochemistry & Biophysics
Journal title
BIOSCIENCE BIOTECHNOLOGY AND BIOCHEMISTRY
ISSN journal
09168451 → ACNP
Volume
63
Issue
11
Year of publication
1999
Pages
1991 - 1992
Database
ISI
SICI code
0916-8451(199911)63:11<1991:RASO(W>2.0.ZU;2-W
Abstract
(S)-1-(2-Naphthyl)ethanol was yielded by immobilized pea (Pisum sativum L.) protein (IPP) from (R,S) 2-naphthyl ethanol (>99% ee, yield; about 50%), i n which the (R)-enantiomer was selectively oxidized to 2-acetonaphthone. IP P could be reused consecutively at least three times without any decrease o f yield and optical purity.