Calcination effect on magnesium hydroxide and aluminium hydroxide for the development of magnesium aluminate spinel

Spinellisation and densification of magnesium aluminate spinel was studied. Magnesium hydroxide and aluminium hydroxide were calcined separately betwe en 900 and 1600 degrees C. Stoichiometric mixtures of the uncalcined and ca lcined materials were sintered between 1550 degrees C to 1750 degrees C. Sp inellisation was found to be reduced with increasing calcination temperatur e bt sintering at 1750 degrees C produces similar spinellisation for differ ent batches due to higher diffusivities of the diffusing species. Above 99% spinellisation was obtained for the uncalcined batch sintered at 1750 degr ees C. Densification was also found to be greatly dependent on calcination temperature. Control of reactivity by calcination and slower rate of sinter ing have reduced the negative effects of the single stage sintering and a m aximum of 91% densification has been found for the batch, with materials ca lcined at 1400 degrees C. (C) 1999 Elsevier Science Ltd and Techna S.r.l. A ll rights reserved.