Nickel mediated sulfur-selenium and sulfur-sulfur bond formation

Authors
Lai, CH Reibenspies, JH Darensbourg, MY
Citation
Ch. Lai et al., Nickel mediated sulfur-selenium and sulfur-sulfur bond formation, CHEM COMMUN, (24), 1999, pp. 2473-2474
Citations number
13
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
24
Year of publication
1999
Pages
2473 - 2474
Database
ISI
SICI code
1359-7345(1999):24<2473:NMSASB>2.0.ZU;2-U
Abstract
Electrophilic addition of the PhSeCl to a nickel dithiolate yields S,S'-bis (phenylselenenyl-N,N'-bis(mercaptoethyl)-1,5-diazacyclooctane nickel(II) di chloride and a dimeric, intermolecular bis-disulfide which results from lig and oxidation.