One step synthesis of [7]metacyclophanediyne complexes from bis(propargyldicobalt) dication equivalents

Authors
Citation
R. Guo et Jr. Green, One step synthesis of [7]metacyclophanediyne complexes from bis(propargyldicobalt) dication equivalents, CHEM COMMUN, (24), 1999, pp. 2503-2504
Citations number
38
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
24
Year of publication
1999
Pages
2503 - 2504
Database
ISI
SICI code
1359-7345(1999):24<2503:OSSO[C>2.0.ZU;2-E
Abstract
The BF3. OEt2 mediated addition reactions of electron-rich arenes to 1,3-di alkoxyhepta-2,5-diyne(dodecacarbonyl)-tetracobalt complex 1 directly afford [7]metacyclophanediyne(dodecacarbonyl)tetracobalt complexes.