Asymmetric synthesis of 2,3-disubstituted oxepanes via acetalization-cyclization of an enantioenriched functionalized allylsilane with aldehydes

Authors
Suginome, M Iwanami, T Ito, Y
Citation
M. Suginome et al., Asymmetric synthesis of 2,3-disubstituted oxepanes via acetalization-cyclization of an enantioenriched functionalized allylsilane with aldehydes, CHEM COMMUN, (24), 1999, pp. 2537-2538
Citations number
14
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
24
Year of publication
1999
Pages
2537 - 2538
Database
ISI
SICI code
1359-7345(1999):24<2537:ASO2OV>2.0.ZU;2-4
Abstract
According to the protocol for the acetalization-intramolecular allylsilane cyclization, a new enantioenriched allylsilane, (R)-(E)-7-(dimethylphenylsi lyl)undec-5-en-1-ol, in the presence of a variety of aldehydes provided ena ntioenriched trans-2,3-disubstituted oxepanes stereoselectively.