Electronic properties of carbon clusters with diameters d between 4 and 110
0 Angstrom were studied by scanning tunneling spectroscopy (STS), Large-siz
ed clusters all showed the zero band gap of graphite. A gap opening was obs
erved for clusters with diameters less than about 15 Angstrom. Energy gaps
up to 650 meV were measured. The experimental results were modeled using a
finite barrier potential for confined electrons, with consideration of the
effective mass. (C) 1999 Elsevier Science B.V. All rights reserved.