A general dissolution model for oxidic solids in water has been suggested.
To confirm this model the dissolution kinetics of well-defined silica spher
es is determined dependent on pH and ionic strength at 40 degrees C. By ana
lyzing dissolution data it is possible to study electrical double layer pro
perties. In this approach, the charge state of the oxide is described by ap
plication of a diffuse layer model. From a theoretical point of view, some
important, general conclusions for the overall rate constant of dissolution
, consisting of three partial rate constants, may be drawn. The characteris
tic parameters such as the pristine point of zero charge, the,acidity const
ants of the surface groups, the saturation concentration, and the partial r
ate constants, could be determined precisely. Experimental results for two
different types of silica are compared. The model is able to elucidate well
the dissolution behavior as a function of time, pH and ionic strength. (C)
1999 Elsevier Science B.V. All rights reserved.