F. Rubio-hernandez et al., An experimental study on the influence of a dynamic Stern-layer on the primary electroviscous effect, COLL SURF A, 159(2-3), 1999, pp. 373-379
Citations number
28
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
The most recent theory by Watterson and White for the primary electroviscou
s effect of a suspension of charged spherical particles has been extended b
y considering the influence of a dynamic Stern-layer. In this work we have
tested the theoretical results by measuring the viscosity of polystyrene su
spensions in different electrolyte concentrations. Zeta potential values ha
ve been obtained by electrophoresis and conductivity experiments using the
theoretical approachs by Mangelsdorf and White that include the Stern-layer
conductance. In order to obtain the same potential values calculated from
these two independent methods, we have fitted the Stern-layer parameters of
our systems, These parameters and zeta values have been used to calculate
the theoretical viscosity. The theoretical results have been compared with
the experimental viscosity data obtained with a semiauthomatic Ubbelohde ca
pillary viscometer. We can conclude that the dynamic Stern-layer model used
in this work has only a slight influence on the correction of the primary
electroviscous effect theory due to Watterson and White. We suggest to stud
y the correction supplied by another dynamic Stern-layer model due to Dukhi
n and Semenikhin, considering its success when is applied to electrophoresi
s. (C) 1999 Elsevier Science B.V. All rights reserved.