Direct synthesis of pseudo-disaccharides by rearrangement of unsaturated disaccharides

Authors
Pearce, AJ Sollogoub, M Mallet, JM Sinay, P
Citation
Aj. Pearce et al., Direct synthesis of pseudo-disaccharides by rearrangement of unsaturated disaccharides, EUR J ORG C, (9), 1999, pp. 2103-2117
Citations number
30
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
ISSN journal
1434193X → ACNP
Issue
9
Year of publication
1999
Pages
2103 - 2117
Database
ISI
SICI code
1434-193X(199909):9<2103:DSOPBR>2.0.ZU;2-C
Abstract
The series of unsaturated disaccharides 10-14 undergo stereoselective reduc tive rearrangement with TIBAL (triisobutylaluminium) to afford (1-->4) and (1-->6) ether-linked pseudo-disaccharides 2-9.