Using periodic gratings etched into the surface of a piezoelectric plate, s
urface acoustic waves (SAW) call be converted into bulk waves and vice vers
a with high efficiency. If parallel grating structures are fabricated on op
posite surfaces of a piezoelectric plate, a SAW also can be directed from o
ne surface to the other. Using such structures, acoustic wave-based sensors
can be designed that utilize SAW for the detection of chemical analytes on
an electrode-free surface, i.e., the back surface. As a result, spurious s
ensor response and electrode aging that may occur when a chemical analyte c
omes in contact with the transducers are minimized. The design principles o
f these grating-based SAW sensors are explained, and the mass sensitivity i
s investigated using chemical vapor deposited thin polymer films, a type of
material used in many practical chemical sensor applications. Experimental
results are presented for the detection of nitrogen dioxide (NO2) in sub-p
pm concentrations.