Cf. Lin et al., Effects of methyl silsesquioxane electron-beam curing on device characteristics of logic and four-transistor static random-access memory, JPN J A P 1, 38(11), 1999, pp. 6253-6257
The as-spun methyl silsesquioxane (MSQ) film cured by an electron beam (e-b
eam) did not show water absorption after a five-day exposure to ambient ail
: MSQ was applied to the triple-level metal (TLM) Logic and double-level me
tal (DLM) foul-transistor (4-T) static random-access memory (SRAM) as inter
metal dielectric by means of the non-etchback process. When MSQ treatment c
onditions were properly controlled, the top layer of the as-spun films was
cured by e-beam exposure while the bottom layer of the film was thermally c
ured for a short period of time. The as-cured MSQ offered good surface plan
arity. In addition, neither via poisoning, bowing nor cracking was observed
. The results showed that, by the application of the e-beam cured MSQ in th
e fabrication of intel connect structures, the cache time of DLM 4-T SRAM c
ould be improved to 10 ns compared with 11.5 ns for the SRAM fabricated usi
ng the conventional furnace cure spin-on-glass (SOG) process (400 degrees C
annealing for one hour). E-beam exposure has little effect on n-channel me
tal-oxide-semiconductor (NMOS) device characteristics, such as saturation c
urrent threshold voltage and channel length. In contrast, e-beam exposure h
as a significant effect on p-channel MOS (PMOS) device characteristics, res
ulting in a shift of the threshold voltage as well as an increase in the ch
annel length. It is notable that the e-beam exposure almost did not affect
NMOS device characteristics in the 4-T SRAM, since the polysilicon load res
istor could serve as a shield against electron bombardment. In such a case,
the resistance of the polysilicon load resistor was significantly decrease
d.