F atoms were generated by a low-power microwave discharge of various Ar/CF4
mixtures in a fast discharge flow. They were used for chemical dry etching
of Si substrate at room temperature. The Variation of etch rate was measur
ed as a function of the microwave power, the Ar or CF4 flow rate, and the d
istance between the center of discharge and the substrate, in order to dete
rmine the optimum conditions. The maximum etch rate was about 700 Angstrom/
min at a microwave power of 80W an Ar flow rate of 3000 seem, a CF4 flow ra
te of 70 seem, and a distance between the center of discharge and the subst
rate of 10 cm. A thin CmFn polymer was deposited on the etching edge at hig
h CF4 flow rates of 80-100 seem.