What is possible with a quadrupolar nuclei in NMR? Co-59 as an example

Authors
Granger, P Hirschinger, J Elbayed, K Sizun, C Kempgens, P Raya, J Rose, J Braunstein, P
Citation
P. Granger et al., What is possible with a quadrupolar nuclei in NMR? Co-59 as an example, J CHIM PHYS, 96(9-10), 1999, pp. 1479-1485
Citations number
9
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE → ACNP
Volume
96
Issue
9-10
Year of publication
1999
Pages
1479 - 1485
Database
ISI
SICI code
Abstract
We have observed cobalt. 59 NMR on tetrahedric clusters in solution and in the solid stale. From the relaxation times in solution, we are able to dedu ce the quadrupolar coupling constants for Ru-99 and to simulate the Co-59 s pectrum in the solid state for the basal atoms of Co-4(CO)(12) which has ne ver been observed. This short review shows the interest of high fields appl ied to quadrupolar nuclei.