The standard state of cerium

Citation
Ka. Gschneidner et Vk. Pecharsky, The standard state of cerium, J PH EQUIL, 20(6), 1999, pp. 612-614
Citations number
5
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
JOURNAL OF PHASE EQUILIBRIA
ISSN journal
10549714 → ACNP
Volume
20
Issue
6
Year of publication
1999
Pages
612 - 614
Database
ISI
SICI code
1054-9714(199912)20:6<612:TSSOC>2.0.ZU;2-9
Abstract
Based on two studies carried out about 20 years apart, it was found that th e double close-packed hexagonal beta Ce phase slowly transformed to the fac e-centered cubic gamma Ce phase at room temperature and ambient pressure. T his indicates that gamma Ce is the stable modification at standard temperat ure and pressure (i.e., 298 K and 1 atm), The beta Ce <----> gamma Ce equil ibrium temperature at 1 atm, the heat of transformation, the temperature/pr essure phase diagram, and the heat capacities of beta Ce and gamma Ce are p resented.