gamma-MnO2 for Li batteries Part I. gamma-MnO2: Relationships between synthesis conditions, material characteristics and performances in lithium batteries
S. Sarciaux et al., gamma-MnO2 for Li batteries Part I. gamma-MnO2: Relationships between synthesis conditions, material characteristics and performances in lithium batteries, J POWER SOU, 82, 1999, pp. 656-660
Citations number
12
Categorie Soggetti
Physical Chemistry/Chemical Physics","Environmental Engineering & Energy
With the use of various electrodeposition conditions (concentration and pH
of the bulb MnSO4 solution, temperature, synthetic mode) and thermal treatm
ents, gamma-MnO2 materials exhibiting rather different physico-chemical and
structural characteristics were prepared. Relationships were established b
etween synthesis conditions and such characteristics, showing that to some
extent, these physico-chemical and structural parameters can be tuned. The
electrochemical behavior of lithiated phases obtained upon the first Li ins
ertion into these gamma-MnO2 materials has been investigated. It is shown t
hat the maximum Li reversible intercalation capacity strongly depends on th
e structural parameters (concentration of De Wolff defects and degree of mi
crotwinning) of the starting gamma-MnO2 samples. (C) 1999 Elsevier Science
S.A. All rights reserved.