Two simplified modeling approaches are used to model the combustion of hydr
azinium nitroformate (HNF), N2H5. C(NO2)(3). The condensed phase is treated
by high-activation-energy asymptotics. The gas phase is treated by two lim
it cases: the classical high-activation-energy approximation and the recent
ly introduced low-activation-energy approach. This results in simplificatio
n of the gas-phase energy equation, making an (approximate) analytical solu
tion possible. The results of both models are compared with experimental re
sults of HNF combustion. It is shown that the low-activation-energy approac
h yields better agreement with experimental observations, for example, regr
ession rate and temperature sensitivity, than the high-activation-energy ap
proach.