Ys. Yoon et Hj. Jung, Optical and electrical properties of the PLT films with various compositions deposited by sol-gel process, J SOL-GEL S, 16(1-2), 1999, pp. 29-35
In order to study optical and electrical properties of (Pb1-xLax)TiO3 (PLT)
films with varying La concentration, the PLT films were deposited by sol-g
el process. X-ray diffraction revealed that a pseudocubic phase of the PLT
film became dominant with increasing La concentration due to decrease of la
ttice constant of c-axis. Three-dimensional atomic force microscopy images
showed that the grain size and root mean square surface roughness decreased
by addition of La. The optical band gap of the PLT films became wider when
Pb was substituted with La. The addition of La increased the transparency
of the PbTiO3 film and shifted the threshold for initiation of absorption t
o shorter wavelength. Hysteresis loops of the PLT films showed that remanen
t polarization and coercive field decreased with increasing La concentratio
n. In addition, we modified the surface of the PLT film with La concentrati
on of 5% using a keV oxygen ion beam at different doses. The optical band g
ap of the PLT film was changed by the oxygen ion beam irradiation although
the XRD patterns and the transmittance values were not significantly change
d. In measuring AFM images of the surface of modified PLT film, significant
changes of the grain shape and size were not found. Moreover, polarization
and dielectric constant were not changed after oxygen ion irradiation. The
se results suggested that addition of La could affect the optical and elect
rical properties of the PbTiO3 and PLT films and that surface modification
by oxygen ion beam modification with 1 keV energy can change the surface pr
operty but not bulk property.