We report observations of (CO)-C-13 (J=1-0) and (J=2-1) emission towar
ds 5 evolved OH/IR envelopes. Four of them are known to have very weak
CO emission compared to their infrared flux, and an anomalously high
(J=2-1)/(J=1-0) intensity ratio. Modeling of their (CO)-C-12 and (CO)-
C-13 lines is used to test several possible explanations of this behav
iour. We conclude that it is most likely due to the recent onset of a
superwind phase. Another interesting result of the modeling is the ver
y low C-12/C-13 isotopic ratios we derive in these envelopes, of the o
rder of 3.5 and close to the equilibrium value of the CNO cycle. We in
terpret this as the signature of massive stars at the end of their AGE
phase, The sixth envelope, which shows a much lower (J=2-1)/(J=1-0) i
ntensity ratio, also has a low, marginally larger, C-12/C-13 isotopic
ratio. We conclude that it also is a massive object, but in a slightly
less evolved stage, just before the superwind phase.