The laws of thinning and breaking of a caplliary filament of a high-mo
lecular-weight polymer solution were experimentally and theoretically
investigated, Physical mechanisms involved in the filament breaking ar
e analyzed. Measurements of the time variation of the capillary filame
nt diameter, performed for a variety of polymer solutions, gave result
s consistent with the theoretical model developed, Possibilities to us
e observations of the formation, thinning, and breakage of polymer fil
aments for evaluation of the rheological characteristics of polymer so
lutions.