Design and synthesis of new electro-optic polymers are presented. These pol
ymers have specific refractive index as low as the index of glass ion-excha
nge waveguides. With these materials, a novel hybrid structure can be desig
ned for optical modulation in passive waveguide. The low index is obtained
by copolymerization of an electro-optic monomer and two fluorinated comonom
ers. The result is a copolymer with an index close to 1.50, high electro-op
tic coefficient and good technical properties. (C) 1999 Elsevier Science B.
V. All rights reserved.