V. Crupi et al., EG-PEO and EG homologue-PEO systems: an example of different solute-solvent interactions depending on monomer end groups, PHIL MAG B, 79(11-12), 1999, pp. 1877-1880
We performed viscosity measurements, at T = 50 degrees C, on poly(ethylene
oxide) (H-(O-CH2-CH2)(n)-OH) at different molecular weight, dissolved in et
hylene glycol (H-(O-CH2-CH2)-OH) and in one of its homologous systems, name
ly ethylene glycol dimethyl ether (CH3-(O-CH2-CH2)-OCH3). The goal is to in
vestigate the effects of the monomer end groups on solute-solvent interacti
ons and, on this basis, to check the quality of these two solvents by using
the Mark-Houwink-Sakurada scaling law.