Coordinating behaviour of 3-methyl[1,2,3]triazolo[1,5-a]pyridine (tzpy): crystal and molecular structure and electronic properties of [Cu(tzpy)(2)(ONO2)(2)(OH2)]
R. Ballesteros et al., Coordinating behaviour of 3-methyl[1,2,3]triazolo[1,5-a]pyridine (tzpy): crystal and molecular structure and electronic properties of [Cu(tzpy)(2)(ONO2)(2)(OH2)], POLYHEDRON, 18(24), 1999, pp. 3129-3133
The crystal and molecular structure of [Cu(tzpy)(2)(ONO2)(2)(OH2)] (tzpy =
3-methyl[1,2,3]triazolo[1,5-a]pyridine) has been determined by X-ray diffra
ction methods. The crystal structure is built up of discrete [Cu(tzpy)(2)(O
NO2)(2)(OH2)] entities linked through hydrogen bonds. The coordination geom
etry around the copper atom can be described as an elongated and strongly d
istorted octahedron displaying a 4 + 1 + 1* coordination mode (CuN2O2O'O "
chromophore) with one of the nitrate groups acting as bidentate and involve
d in a weak off-the-z-axis coordination. Spectroscopic properties are inter
preted on the basis of the above stereochemistry. (C) 1999 Elsevier Science
Ltd. All rights reserved.