Co-adsorption of anions and low-adsorbing cations within the Alekseev-Popov-Kolotyrkin model

Authors
Damaskin, BB Baturina, OA
Citation
Bb. Damaskin et Oa. Baturina, Co-adsorption of anions and low-adsorbing cations within the Alekseev-Popov-Kolotyrkin model, RUSS J ELEC, 35(11), 1999, pp. 1182-1185
Citations number
20
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
RUSSIAN JOURNAL OF ELECTROCHEMISTRY
ISSN journal
10231935 → ACNP
Volume
35
Issue
11
Year of publication
1999
Pages
1182 - 1185
Database
ISI
SICI code
1023-1935(199911)35:11<1182:COAALC>2.0.ZU;2-O
Abstract
Co-adsorption of an anion and a low-adsorbing cation is analyzed within the Alekseev-Popov-Kolotyrkin model supplemented by two virial isotherms (APK2VI). In the case of a high attractive interaction of specifically adsorbed anions and cations, the condition \dE(q = 0)/dlnc/ > RT/F is insufficient to confirm the Esin-Markov effect. The drawback of APK+2VI is in the existe nce of a potential range where the system of isotherms has no solution.