Citation
Vv. Semenov et al., Reaction of tris(trimethylsilyl)silane with pentacarbonyliron, RUSS J G CH, 69(6), 1999, pp. 910-912
Citations number
15
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632
→ ACNP
Volume
69
Issue
6
Year of publication
1999
Pages
910 - 912
Database
ISI
SICI code
1070-3632(199906)69:6<910:ROTWP>2.0.ZU;2-J
Abstract
Heating of pentacarbonyliron with tris(trimethylsilyl)silane results in lib
eration of hydrogen and formation of hexakis(trimethylsilyl)disilane. Photo
initiated reaction of the same compounds begins with oxidative addition of
the silicon hydride to the iron complex with liberation of carbon(II) oxide
. Subsequent transformations of the adduct lead to formation of bis(trimeth
ylsilyl)silanediyitricarbonylhybrido(trimethylsilyl)iron which can be stabi
lized as an adduct with hexamethylphosphoramide.