Nitroalkanes as initiators of radical chain processes in chemistry and biology

Citation
Iv. Shugalei et Iv. Tselinskii, Nitroalkanes as initiators of radical chain processes in chemistry and biology, RUSS J G CH, 69(6), 1999, pp. 936-953
Citations number
181
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
69
Issue
6
Year of publication
1999
Pages
936 - 953
Database
ISI
SICI code
1070-3632(199906)69:6<936:NAIORC>2.0.ZU;2-J
Abstract
The mechanisms of radical ion transformations of nitroalkanes both in vitro and in vivo are considered. These reactions which have radical ion feature s generate nitroalkyl hydroperoxides capable of taking part in chain-branch ing processes. Active oxygen species which are also generated in the course of the reaction are involved in the subsequent processes.