17-acetoxy derivatives of immunotropic 8-aza-D-homogona-12,17a-diones. Annelation of 3,4-dihydroquinolines with 4-acetoxy-2-acetyl-1,3-cyclohexanedione

Authors
Gulyakevich, OV Zaitsev, VG Mikhal'chuk, AL
Citation
Ov. Gulyakevich et al., 17-acetoxy derivatives of immunotropic 8-aza-D-homogona-12,17a-diones. Annelation of 3,4-dihydroquinolines with 4-acetoxy-2-acetyl-1,3-cyclohexanedione, RUSS J G CH, 69(6), 1999, pp. 1000-1001
Citations number
10
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
69
Issue
6
Year of publication
1999
Pages
1000 - 1001
Database
ISI
SICI code
1070-3632(199906)69:6<1000:1DOI8A>2.0.ZU;2-4
Abstract
Regioselective fusion of 3,4-dihydroisoquinolines to 4-acetoxy-2-acetyl-1,3 -cyclohexanedione yields hitherto unknown 17-acetoxy-8-aza-D-homogona-12,17 a-diones. The reaction is not stereospecific, and two racemic pairs of dias tereoisomers are formed, (9R,17R)/(9S,17S) and (9R,17S)/(9S,17R).