High-pressure synthesis of sodium bismuthide Na3Bi

Authors
Kulinich, SA Leonova, ME Sevast'yanova, LG Gulish, OK Burdina, KP
Citation
Sa. Kulinich et al., High-pressure synthesis of sodium bismuthide Na3Bi, RUSS J G CH, 69(5), 1999, pp. 681-683
Citations number
11
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
69
Issue
5
Year of publication
1999
Pages
681 - 683
Database
ISI
SICI code
1070-3632(199905)69:5<681:HSOSBN>2.0.ZU;2-7
Abstract
High-pressure synthesis of sodium bismuthide from metallic sodium and bismu th was studied. The pressure required for compression of a mixture of antim ony or bismuth with an alkali metal to the volume of the corresponding alka li metal antimonide or bismuthide at room temperature was calculated. For s odium bismuthide these calculations were confirmed experimentally.