Complexes of 3d and 4d elements with ethylenediamine and N,N '-ethylenediaminetetraacetic acid in catalytic reduction of silver halides in AgHlg-gelatin-immobilized matrix systems

Authors
Citation
Ov. Mikhailov, Complexes of 3d and 4d elements with ethylenediamine and N,N '-ethylenediaminetetraacetic acid in catalytic reduction of silver halides in AgHlg-gelatin-immobilized matrix systems, RUSS J G CH, 69(5), 1999, pp. 721-725
Citations number
21
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
69
Issue
5
Year of publication
1999
Pages
721 - 725
Database
ISI
SICI code
1070-3632(199905)69:5<721:CO3A4E>2.0.ZU;2-2
Abstract
The effect of 3d and 4d element complexes with ethylenediamine and N,N'-eth ylenediaminetetraacetic acid on the rate of AgHlg --> Ag redox process in t he preliminarily photoactivated matrices was studied. In the analysis of th is effect the most decisive is the energy of stabilization of given complex in the ligand field. The correlation of the degree of this effect and stab ilization energy was evaluated.