Quantitative estimation of the role played by aqueous-organic solvents in formation of monocrown complexes of sodium and potassium ions

Authors
Bondarev, NV
Citation
Nv. Bondarev, Quantitative estimation of the role played by aqueous-organic solvents in formation of monocrown complexes of sodium and potassium ions, RUSS J PH C, 73(6), 1999, pp. 899-904
Citations number
10
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY
ISSN journal
00360244 → ACNP
Volume
73
Issue
6
Year of publication
1999
Pages
899 - 904
Database
ISI
SICI code
0036-0244(199906)73:6<899:QEOTRP>2.0.ZU;2-X
Abstract
A thermodynamic analysis of reagent solvation on the rational scale was per formed for the purpose of a quantitative comparison of the roles played by aqueous-organic solvents (water-methanol, water-2-propanol, and water-aceto nitrile) in complex formation equilibria between sodium and potassium ions and 18-crown-6 and dibenzo-18-crown-6.