Clean magnesium surfaces were created by evaporating Mg onto silicon wafers
. When exposing the Mg surface to a low oxygen partial pressure, an exoelec
tron emission (EEE) is observed after a time delay of the order of several
hours after evaporation. On a much shorter time scale, similar effects in e
xoemission from Mg and alkali metals have been observed previously. The res
ults are discussed within a 'potential emission' model of exoelectrons duri
ng oxygen capture at the pure Mg surface, but extending the model by includ
ing an escape mechanism. A macroscopic quantitative description of the mode
l is given, which is in good agreement with our measurements. (C) 1999 Else
vier Science B.V. All rights reserved.