Synthesis, properties, and crystal and molecular structure of the complex [Co(tren)(dmg)]center dot ClO4

Authors
Zhan, SZ Xi, RB Miao, YQ Guo, D Wang, DY Yuan, CW
Citation
Sz. Zhan et al., Synthesis, properties, and crystal and molecular structure of the complex [Co(tren)(dmg)]center dot ClO4, SYN REAC IN, 29(10), 1999, pp. 1769-1777
Citations number
12
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
ISSN journal
00945714 → ACNP
Volume
29
Issue
10
Year of publication
1999
Pages
1769 - 1777
Database
ISI
SICI code
0094-5714(1999)29:10<1769:SPACAM>2.0.ZU;2-4
Abstract
The: new complex [Co(tren)(dmg)]. ClO4 (tren = 2,2',2"-triaminotriethylamin e. H(2)dmg = dimethylglyoxime) has been synthesized and its properties have been studied by IR and electronic spectroscopy. Cyclic voltammetry shows t he presence of one redox couple. Its crystal structure has been determined bq X-ray diffraction.