CHARACTERIZATION OF A NEW CALCIUM ULTRAPHOSPHATE, CA-3(P5O14)(2)

Authors
GOZEL G KIZILYALLI M KNIEP R
Citation
G. Gozel et al., CHARACTERIZATION OF A NEW CALCIUM ULTRAPHOSPHATE, CA-3(P5O14)(2), Journal of solid state chemistry, 129(2), 1997, pp. 196-199
Citations number
32
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Journal of solid state chemistry → ACNP
ISSN journal
00224596
Volume
129
Issue
2
Year of publication
1997
Pages
196 - 199
Database
ISI
SICI code
0022-4596(1997)129:2<196:COANCU>2.0.ZU;2-K
Abstract
Ca-3(P5O14)(2) was prepared by the solid-state reaction of CaBPO5 and (NH4)(2)HPO4 as small single crystals. The cell dimensions were calcul ated in the monoclinic system using its powder diffraction pattern and were found to be a=8.695(5), b=8.999(6), c=12.940(1) Angstrom, beta=9 1.89(5)degrees, and the space group is probably P2(1)/m (No. 11) or P2 (1) (No. 4) with Z=4. The compound was characterized by SEM, IR spectr oscopy, and EDX analysis of the single crystals. (C) 1997 Academic Pre ss.