Oxidation of a dilute aqueous solution of a model azo dye pollutant (Orange
II) was studied in batch and continuous well-mixed (CSTR) reactors. Both r
eactors operate at 200 - 250 degrees C, and total pressures up to 50 bar an
d at oxygen partial pressure from 10 to 30 bar. The model pollutant concent
rations were in a range between 100 and 1,000 mg/L, which may be found in i
ndustrial wastewaters. The dye oxidation undergoes a parallel-consecutive r
eaction pathways, in which it first decomposes thermally and oxidatively to
aromatic intermediates and via organic acids to the final product carbon d
ioxide. To develop a kinetic equation capable of predicting organic carbon
reduction, all organic species present in solution were lumped by total org
anic carbon (TOC). The lumped oxidation rate in batch reactor exhibited sec
ond-order behavior, whereas in the CSTR it was found linearly proportional
to its TOC concentration. The lump behavior in batch reactor was dominated
by the refractory low molecular mass aliphatic acids formed during the oxid
ation.