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Direct electron transfer (DET) between redox enzymes and electrodes found t
he basis for third generation biosensors. Recent investigations in the auth
ors' laboratories on the bioelectrochemistry of heme-containing proteins an
d enzymes, primarily peroxidases, but also cellobiose dehydrogenase, will b
e reviewed. (C) 1999 Elsevier Science B.V. All rights reserved.