Schiff base insertion in titanium alkyls; reduction of imine functions by benzyl addition

Citation
Sj. Coles et al., Schiff base insertion in titanium alkyls; reduction of imine functions by benzyl addition, CAN J CHEM, 77(12), 1999, pp. 2095-2098
Citations number
16
Categorie Soggetti
Chemistry
Journal title
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE
ISSN journal
00084042 → ACNP
Volume
77
Issue
12
Year of publication
1999
Pages
2095 - 2098
Database
ISI
SICI code
0008-4042(199912)77:12<2095:SBIITA>2.0.ZU;2-A
Abstract
TiBz(4) reacts with N-2-fluorenyl(salicylideneimine) to afford a crystallog raphically characterized titanium(IV) complex containing two conventional b identate Schiff base ligands and two O-bound ligands in which the imine fun ction has been reduced by the addition of benzyl and hydrogen moieties.