Ad. Buckingham et Y. Tantirungrotechai, The second dielectric virial coefficient of the dipolar Gay-Berne fluid, CAN J CHEM, 77(11), 1999, pp. 1946-1950
Citations number
20
Categorie Soggetti
Chemistry
Journal title
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE
We report the second dielectric virial coefficient B-epsilon of a nonpolari
zable dipolar Gay-Berne fluid. The second dielectric virial coefficient is
evaluated for several sets of shape parameters and temperature. The second
dielectric virial coefficient for rodlike molecules is negative while it is
large and positive for disklike molecules. It decreases to zero on increas
ing the temperature.