The WAR algorithm, a methodology for determining the potential environmenta
l impact (PEI) of a chemical process, is presented with modifications that
account for the PEI of the energy consumed within that process. From this t
heory, four PEI indexes are used to evaluate the environmental friendliness
of a process design. These indexes are used in a comparative manner in the
process design stage to help minimize the environmental impact of that pro
cess. Eight PEI categories (four global and four toxicological) are used in
the evaluation of the PEI indexes. Details for relating these categories t
o known or measured quantities are also presented. An illustrative case stu
dy is presented which provide an example for the intended use of the WAR al
gorithm within the scope of process design and simulation. (C) 1999 Elsevie
r Science Ltd. All rights reserved.