Degradation of the herbicide, acetochlor in surface and sub-surface soils under field and laboratory conditions

Citation
Pc. Vaughan et al., Degradation of the herbicide, acetochlor in surface and sub-surface soils under field and laboratory conditions, HUMAN AND ENVIRONMENTAL EXPOSURE TO XENOBIOTICS, 1999, pp. 481-490
Citations number
20
Categorie Soggetti
Current Book Contents
Year of publication
1999
Pages
481 - 490
Database
ISI
SICI code
Abstract
Rapid and comparable rates of acetochlor degradation were found in surface and subsoils incubated under both field and laboratory conditions. For the field-incubation study, undisturbed soil cores were sampled vertically from surface (0-30 cm) and two sub-surface (30-76 cm and 260-305 cm) depths. So il cores were treated in the field with C-14-labelled acetochlor and reburi ed in the field at a depth similar to their depth of abstraction. Laborator y-incubated soils from the same site were incubated under two separate sets of conditions: 20 degrees C/moisture content pF2, and temperature/moisture conditions similar to field incubation conditions. In both studies, acetoc hlor was applied to surface soil at a rate of 2.9 kg ha(-1), and to the sub soils at approximately 5% of this rate. Rates of acetochlor degradation wer e faster in subsoils (7.5 to 13.8 days) than surface soil (18.3 days) in fi eld-incubated soils. Furthermore, field degradation rates were comparable t o laboratory-generated data (subsoils 2-32 days; surface soil 8-15 days). T his confirms the validity of performing laboratory-based degradation studie s to determine pesticide DT50 values in subsoils.