Pc. Vaughan et al., Degradation of the herbicide, acetochlor in surface and sub-surface soils under field and laboratory conditions, HUMAN AND ENVIRONMENTAL EXPOSURE TO XENOBIOTICS, 1999, pp. 481-490
Rapid and comparable rates of acetochlor degradation were found in surface
and subsoils incubated under both field and laboratory conditions. For the
field-incubation study, undisturbed soil cores were sampled vertically from
surface (0-30 cm) and two sub-surface (30-76 cm and 260-305 cm) depths. So
il cores were treated in the field with C-14-labelled acetochlor and reburi
ed in the field at a depth similar to their depth of abstraction. Laborator
y-incubated soils from the same site were incubated under two separate sets
of conditions: 20 degrees C/moisture content pF2, and temperature/moisture
conditions similar to field incubation conditions. In both studies, acetoc
hlor was applied to surface soil at a rate of 2.9 kg ha(-1), and to the sub
soils at approximately 5% of this rate. Rates of acetochlor degradation wer
e faster in subsoils (7.5 to 13.8 days) than surface soil (18.3 days) in fi
eld-incubated soils. Furthermore, field degradation rates were comparable t
o laboratory-generated data (subsoils 2-32 days; surface soil 8-15 days). T
his confirms the validity of performing laboratory-based degradation studie
s to determine pesticide DT50 values in subsoils.